Effect of Zn, Cu, Cr and Pb Chlorides on the Formation of Tricalcium Aluminate Trisulfate Hydrate

Abstract

The effect of addition of Zn, Cu, Pb and Cr chlorides as admixtures on the hydration reaction of the system 3CaO•Al2O3-gypsum with molar ratio 1:3 was studied. Different ratios of each salt were used, namely 0.5%, 2% and 4% by weight of the solid mixture. Hydration reaction was carried out at 35℃ for various time intervals from 0.5 h to up to 7 d. Hydration rate of the system 3CaO•Al2O3-CaSO4•2H2O in absence and presence of different salts was studied via the determination of the combined water contents. X-ray diffraction analysis showed that the ettringite was the only hydration product formed in the different mixes. The hydration products were investigated by scanning electron microscopy (SEM) and thermal gravimetric analysis. The results indicated that the rate of formation of ettringite and its microstructure depend on the admixture and its dosage.